Haruto Tokishima, a high school student, discovers Valvrave, a mysterious and very powerful machine, and after controlling it Haruto becomes immortal.
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| Title | Air Date | Duration | ||
|---|---|---|---|---|
| Season 1 | Episode 1 | Revolutionary Transfer Student | 2013-04-12 | 25 min |
| Season 1 | Episode 2 | Beyond 666 | 2013-04-19 | 25 min |
| Season 1 | Episode 3 | L-Elf's Prophecy | 2013-04-26 | 25 min |
| Season 1 | Episode 4 | The Valvrave is the Hostage | 2013-05-03 | 25 min |
| Season 1 | Episode 5 | The Sakimori Academy Sings | 2013-05-10 | 25 min |
| Season 1 | Episode 6 | Saki Comeback | 2013-05-17 | 25 min |
| Season 1 | Episode 7 | Haruto Under the Ruins | 2013-05-24 | 25 min |
| Season 1 | Episode 8 | Princess of Light | 2013-05-31 | 25 min |
| Season 1 | Episode 9 | Dog and Thunder | 2013-06-07 | 25 min |
| Season 1 | Episode 10 | Campaign Promise of Love | 2013-06-14 | 25 min |
| Season 1 | Episode 11 | Military Tribunal #54 | 2013-06-21 | 25 min |
| Season 1 | Episode 12 | The Heretic Activates | 2013-06-28 | 25 min |
| Season 2 | Episode 1 | A Cursed Bond | 2013-10-11 | 25 min |
| Season 2 | Episode 2 | Siblings in the Atmosphere | 2013-10-18 | 25 min |
| Season 2 | Episode 3 | Return to Karlstein | 2013-10-25 | 25 min |
| Season 2 | Episode 4 | Marie Released | 2013-11-01 | 25 min |
| Season 2 | Episode 5 | The Abyss of the Runes | 2013-11-08 | 25 min |
| Season 2 | Episode 6 | A Father's Wish | 2013-11-15 | 25 min |
| Season 2 | Episode 7 | Tears Like Falling Snow | 2013-11-22 | 25 min |
| Season 2 | Episode 8 | The Holy Spirits Exposed | 2013-11-29 | 25 min |
| Season 2 | Episode 9 | The Cost of Lies | 2013-12-06 | 25 min |
| Season 2 | Episode 10 | Fist of the Moon | 2013-12-13 | 25 min |
| Season 2 | Episode 11 | Module 77 Recapture Strategy | 2013-12-20 | 25 min |
| Season 2 | Episode 12 | Revolution to the Future | 2013-12-27 | 25 min |
| Visual Effects | Shuji Shinoda | CGI Director |
| Visual Effects | Hitomi Ikeda | Color Designer |
| Art | Masatoshi Kai | Art Direction |
| Visual Effects | Takashi Miyamoto | Mechanical Designer |
| Visual Effects | Takayuki Yanase | Mechanical Designer |
| Visual Effects | Kunio Okawara | Mechanical Designer |
| Camera | Yui Tanaka | Director of Photography |
| Art | Takuya Io | Prop Designer |
| Crew | Shinya Shibata | Systems Administrators & Support |
| Art | Kentaro Waki | Assistant Director of Photography |
| Sound | ELISA | Theme Song Performance |
| Visual Effects | Kenji Teraoka | Mechanical Designer |
| Visual Effects | Naohiro Washio | Mechanical Designer |
| Visual Effects | Makoto Ishiwata | Mechanical Designer |
| Writing | Ichiro Okouchi | Series Composition |
| Visual Effects | Tatsuya Suzuki | Supervising Animation Director |
| Sound | Masafumi Mima | Sound Director |
| Sound | Nana Mizuki | Theme Song Performance |
| Sound | Takanori Nishikawa | Theme Song Performance |
| Visual Effects | Katsura Hoshino | Character Designer |
| Visual Effects | Tatsuya Suzuki | Character Designer |
| Directing | Ko Matsuo | Series Director |
| Sound | Akira Senju | Original Music Composer |
